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31. Sodium methoxide used as catalyst for the synthesis of methyl formate by carbonylation of methanol was studied, and effect of three kinds of promoter was investigated.
32. The main deactivation reason of catalyst in low temperature methanol synthesis is that CH 3ONa is transformed to weaker bases such as sodium formate and methyl carbonate.
33. The Ni(II) cation has a distorted octahedral geometry defined by five N atoms from two dimethylglyoxime molecules and two O atoms from two formate anions.
34. Formate and H2/CO2 could be utilized as substrate but not acetate, methanol, trimethylamine or secondary alcohols.
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